The best of health

A few key elements are vital for life. Quite a few more – often referred to as ‘trace elements’ - are needed in tiny amounts to ensure our continuing good health.

But there are others that we really don’t want to find in our diet. These are the poisonous elements that, in some cases, can be lethal even in minute doses. They might not actually kill us outright but some can be chronically debilitating or cause brain and nerve damage.

Despite their alarming properties, quite a few of these unpleasant elements have found their way into medicines, cosmetics and art materials over the centuries, with often predictable results…

Beyond the pale

Beyond the pale

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Arsenic tonics

Arsenic tonics

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Mercury and medicines

Mercury and medicines

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Heavy metal relief

Heavy metal relief

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Milk of Magnesia

Milk of Magnesia

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Pipes, pumps and plumbum

Pipes, pumps and plumbum

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Nasty stuff

Nasty stuff

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Taking temperatures

Taking temperatures

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Dying for your art

Dying for your art

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Just a trace

Just a trace

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Beyond the pale

Stillman’s Skin Bleach Cream contains 5000 times the legal maximum for mercury in cosmetics.
Stillman’s Skin Bleach Cream contains 5000 times the legal maximum for mercury in cosmetics.
The mineral cerussite, or white lead carbonate, was dissolved in vinegar to form ceruse.
The mineral cerussite, or white lead carbonate, was dissolved in vinegar to form ceruse.

For thousands of years people have applied cosmetics to their faces in the pursuit of beauty. European aristocratic women at one time applied ceruse, a fine white powder made from lead carbonate, to their complexions to give the appearance of pale skin. This could have devastating results, causing the death of more than one lady of high society. Maria Countess of Coventry, originally from Castlecoote, Co. Roscommon, died from cosmetic-induced lead poisoning in 1760, aged just 27. Ceruse had already been classified as a poison more than a century earlier but it continued to be used as a cosmetic for many more decades.

The thought that people would use cosmetics containing toxic heavy metals might seem preposterous, but it still goes on. Mercury affects the nervous system and its legal limit in cosmetics is just 1 part per million (0.0001%). Stillman’s Skin Bleach Cream contains 4800 parts per million of mercury, almost 0.5%. Although banned across the the UK and most of Europe, it is still manufactured and widely sold on the internet.

 

Arsenic tonics

Triple arsenate pills, with strychnine! It is not clear what ailment these might have been taken for.
Triple arsenate pills, with strychnine! It is not clear what ailment these might have been taken for.
The mineral orpiment, arsenic sulfide, was ground into a powder for use as an artists’ pigment.
The mineral orpiment, arsenic sulfide, was ground into a powder for use as an artists’ pigment.

Arsenic is a notorious poison. In the 19th Century it was often referred to as “inheritance powder” because it was an effective poison that was difficult to detect. Deliberate poisoning is now thankfully rare but in some parts of the world groundwater supplies are naturally contaminated with arsenic. This can cause significant health problems for those consuming the water.

Bizarrely, arsenic has often been taken as a tonic to treat a whole range of maladies, from arthritis to malaria. In very small quantities it may even do some good since it stimulates the production of haemoglobin, the key ingredient that transports oxygen in the blood.

 

Mercury and medicines

Image: Calomel was used to treat many different maladies in people of all ages and came in a range of different flavours.
Calomel was used to treat many different maladies in people of all ages and came in a range of different flavours.

Mercury is a highly toxic heavy metal. Before the advent of modern antibiotics mercury compounds were widely used to treat various bacterial diseases. Recommended doses commonly contained levels of mercury that were thousands of times higher than the 'safe' limit now recognised. The hope was that it would kill the bacteria before it killed the patient!

Calomel, a compound of mercury and chlorine, was used to treat a host of ailments from constipation and intestinal worms to syphilis and malaria. It has a sweet taste, rather like honey, which is the origin of the ‘mel’ part of the name . It was even used in teething powders as recently as 1954, causing the death of numerous infants, yet Calomel was not removed from official drug lists in the UK until 1958!

 

Heavy metal relief

Image: A section of the Periodic Table, with ‘Poisoners’ Corner’ along the bottom row.
A section of the Periodic Table, with ‘Poisoners’ Corner’ along the bottom row.

One group of heavy metals lie together in an area of the Periodic Table sometimes called “Poisoners’ Corner”. Mercury, Thallium and Lead have been responsible for many deaths, while Polonium is notorious for being the exotic poison that killed Alexander Litvinenko in 2006. Nestled in amongst these killers is the element Bismuth, a heavy metal that seems to buck this deadly trend. Far from being a deadly poison, compounds of bismuth have been used for many decades to settle upset stomachs without any apparent ill effects.

An artificially grown Bismuth crystal about 10 cm across.
An artificially grown Bismuth crystal about 10 cm across.
Pills containing Bismuth compounds have been used to settle stomachs for more than a century.
Pills containing Bismuth compounds have been used to settle stomachs for more than a century.

 

Milk of Magnesia

Milk of Magnesia bottles
Milk of Magnesia bottles
Sir James Murray of Culnady, Co. Londonderry, inventor of Milk of Magnesia.
Sir James Murray of Culnady, Co. Londonderry, inventor of Milk of Magnesia.

The familiar blue glass (which owes its colour to cobalt oxide) bottles of Milk of Magnesia on pharmacy shelves have for more than a century been a welcome site for dyspeptic customers. The key ingredient in both the white liquid ‘milk’, and the tablets, is magnesium hydroxide. This is effective at neutralising digestive acids and settling upset stomachs.

A “condensed solution of fluid magnesia” (a compound of magnesium with hydrogen and oxygen) was first used to treat stomach pain in 1829. Its inventor, Sir James Murray (1788-1871), was born in Culnady, Co. Londonderry. He worked in Belfast for some years before moving to Dublin. Murray Street, beside Belfast Academical Institute, is named after him. The brand name Milk of Magnesia was first used in 1872, by Charles Henry Phillips, and is still in use today.

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Pipes, pumps and plumbum

Image: This 19th Century cast-iron water pump is attached at its base to a lead pipe. The pump itself is painted with red-lead oxide paint.
This 19th Century cast-iron water pump is attached at its base to a lead pipe. The pump itself is painted with red-lead oxide paint.

The Latin word for lead is plumbum, hence its chemical symbol Pb. It is a soft metal that can easily be fashioned into pipes. It has been used since Roman times for this purpose, from which we get the word ‘plumbing’. Lead also is a very poisonous metal, causing damage to the brain and nervous system. In past times lead pipes and pumps could cause low level lead poisoning among people in general; lead paint and toys could poison children that unknowingly chewed on them. In the 20th Century it was the addition of lead to petrol that caused chronic low-level lead poisoning on a global scale.

 

Nasty stuff

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Taxidermy mounts (stuffed mammals and birds) can suffer unwanted attention from much smaller creatures that like to munch on old feathers and fur. To prevent their beautiful mounts from ending up looking rather dog-eared, 19th Century taxidermists would sprinkle them with a fine dusting of arsenic and then seal them beneath a glass dome. This was very effective at poisoning these unwanted pests, but could also be deleterious to the health of taxidermists. Even the museum’s conservators have to treat these displays with care once the glass dome has been removed.

 

Taking temperatures

Mercury thermometer
Mercury thermometer
Galinstan (Gallium-Indium-Tin alloy) thermometer.
Galinstan (Gallium-Indium-Tin alloy) thermometer.

Mercury is the only metallic element that is liquid at normal room temperatures and, as a good conductor of heat, it is ideal for thermometers. But it also is a very toxic element and so today mercury thermometers are seldom found outside of scientific laboratories. Most thermometers that appear to contain mercury actually contain an alloy (mixture) of three metals – tin, indium and gallium – called Galinstan, that remains liquid at temperatures down to -19oC.

 

Dying for your art

Image: These brilliant cadmium pigments are compounds of the metal with sulfur and/or selenium.
These brilliant cadmium pigments are compounds of the metal with sulfur and/or selenium.

For centuries artists have sought new pigments with improved qualities, such as brightness, opacity, or resistance to fading. If it involved using hazardous materials – and it often did – then it was seen as a necessary evil. The true nature of some pigments was disguised; Paris Green was an arsenic compound and vermillion was mercury sulfide. The identity of many others was not, such as Chrome Orange or Cadmium Scarlet. Unfortunately, many artists have a tendency to lick their paintbrushes…

 

Just a trace

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Iodine is a trace element vital for the healthy functioning of your thyroid gland and so, for this reason, is often added in small amounts to table salt. But for fungi, bacteria and many other microorganisms, such as parasitic amoebae, it is bad news and an effective way of killing them. A solution of iodine in water is widely used to sterilise wounds and to kill harmful microorganisms in drinking water.